Assistant Professor of Chemistry
Department of Chemistry and Mathematics
10501 FGCU Blvd South
Fort Myers, FL 33967
Email: kdaviesBLARG@fgcu.edu (remove THIS part from address - my spam filter...)
Phone: 239-590-1459 Fax: 239-590-7200
Jump to: Key Research Interests - Chemical Imaging
Key Research Interests - Landmine Degredation
Analyzing plastics taken from
a landmine while in Cambodia
|Key Research Interests:|
- Photoacoustic Imaging Agents and Chemical Reporters
into our body is like looking into a fogbank - light is scattered
around, making it difficult to see fine features inside. In addition,
most tissue looks pretty similar to most imaging technologies, making
it difficult to identify things like tumors, blood vessels, etc.,
depenging on the technique being used.
imaging can overcome many of these issues, but is a 'new' technology,
and needs a toolkit of molecules to allow us to see specific internal
features, and make chemical measurements without 'poking' the body.
- The photoacoustic effect, "Photo-" part:
you leave a containter with a dark lid on a picnic table, the lid
bulges out - because the lid turned the light into heat, and the
contents expanded when they got hotter. A dark lid absorbs more light
- if we make it a color that doesn't absorb, we 'turn off' the effect.
- ...the "-acoustic" part:
the lab, we use very short (picosecond) pulses of light; instead of
slowly bubbling the lid like in the previous example, it happens
suddenly, like in a firecracker - the sudden heat-expansion makes a
pressure wave (i.e. a sound). If we have a bunch of microphones spaced
out in a line, we can tell where the sound came from based on how long
it took the sound to get to the microphone.
- We are identifying molecules that will be useful for this aparoach - they have these general requirements:
- High molar absorptivity (i.e. they must be 'darkly stained'
should be non-fluorescent, or not very fluorescent (and energy given
off as light is NOT given as heat, and gives weaker signals)
should not break down when hit with light (best case, we've burned out
our signal; worst case, we made a new compound that causes damage of
- The heat-deposition processes should happen much
faster than the resolution of the microphone, or the molecule may
appear deeper in the skin than it actually is.
molecules should also allow us to rapidly make measurements in any
other 'foggy-looking' sample (e.g. river water), allowing rapid
measurements in these samples without filtering, etc.
- Landmine Components, and how the Environment Breaks Them Down
- Our report can be read at: http://maic.jmu.edu/aging/aging_intro.html
- Very briefly, landmines are commonly made from some combination of plastics and metals (occasionally, even wood casings.)
Different components interact with their enviornments at
different rates, leading to the eventual breakdown of the landmine.
From our perspective, this breakdown is desirable: mines
developed since the 1970's are largely low-metal mines that are
challenging to detect, and require labor-intensive (and dangerous)
manual clearance methods. Moneies for these activities are in
short supply vs. the number of emplaces mines that need to be cleared.
If we can better understand how landmines interact with their
environments (rubbers embrittled by wildfires, calcium in groundwater
leaving hard-water deposits between springs and firing pins, rusting,
etc.) we can better allocate clearance efforts by focusing on the 'more
live' fields (though of course, a 40% live field with heavy traffic
will be a higher priority than even a 100%live field in the middle of nowhere!)
team has been successful in identifying the materials in these mines
(they don't exactly come with detailed parts lists w/ suppliers!), and
highlighting some interesting and unexpected results of these
interactions. For example, it is commonly assumed that an agin
mine become less
dangerous with time - but we have found that for a time, mines often
are more dangerous; e.g. the spring holding up the pressue plate has
rusted and weakened, requiring less pressure to trigger the mine, and
making it more likely that stepping near the mine might be enough to detonate it!
A new and pristine PMN-2, the same mine as seen aged to the right.
dramatically changes the appearance of mines; however, most Mine Risk
Education efforts have pictures of the new-and-pristine mine. Our
landmine photos taken during this research should also act as a
valuable resource for teaching civilians what the mine looks like NOW.
Minefield, right next to a foot road, and 20 meters from the landmine training facility where we disassembled the mines.
strikers; these have their springs compressed, until the pressure plate
is pushed diwn. Then, the striker can spring forward and hit the
detonator. On the left are examples that remain in good shape;
moving rightward, the springs have rusted through or become 'glued' to
the striker my mineral deposits.
have burned off the rubber cover on this mine. This allowed roots
to grow beneath the pressure plate. Dirt also was deposited by
the groundwater into the triggering system, 'gumming' it up.
Though the detonator and explosive charge were still live, this
mine was inactivated by degredation over time.
of the interior of the mine shown above. The striker and spring
were in the up/down chamber, and the detonator/spring assembly were in
the left-right chamber. The striker had expanded into the
pressure plate trigger (center) so much that it had to be hammered out
- and could not have fired the mine. Also note that the explosive
(yellow, waxy compound) is in good condition.
CHM 1045 - General Chemistry I (3 cr)
CHM 3120C - Analytical Chemistry with Lab (4 cr)
Additional Courses Taught (@ FGCU, James Madison University, and University of Pittsburgh):
CHM 1045 - General Chemistry I (3 cr), and lab/lecture coordinator
CHM 1045L - General Chemistry I Lab (1 cr)
CHM 3120C - Analytical Chemistry with Lab (4 cr)
Applications of Lasers in Experimental Science (3 cr)
Technology in Science Education (School of Ed., U. of Pitt.) (3 graduate cr)
Advanced General Chemistry II Lab (2 cr)
Physical Chemistry II Lab (1 cr)
Instrumental Analysis Lab (1 cr)
Numerical Methods in Chemistry (1 cr)